1980
DOI: 10.1143/jpsj.49.1046
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An Interionic Potential Model for Crystal Properties of Alkali Hydrides

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1982
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Cited by 14 publications
(6 citation statements)
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“…If the electronic absorptions are situated in the far UV region, then normalnD20 ${{{\rm { n}}}_{{\rm { D}}}^{{\rm { 20}}}}$ is a measure of the overall oscillator strength of the electronic transitions, that is, it is proportional to the number of C atoms. In addition, the position of the OH group also seems to be characteristic [1,3,23–25] . Thus, the decrease of normalnD20 ${{{\rm { n}}}_{{\rm { D}}}^{{\rm { 20}}}}$ as a function of N is more pronounced for tertiary alcohols than for primary or secondary ones indicating a higher oscillator strength and/or a stronger coupling of the solvent oscillators with those of the solute and consequently a stronger redshift in accordance with the previous study [8a] .…”
Section: Resultssupporting
confidence: 87%
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“…If the electronic absorptions are situated in the far UV region, then normalnD20 ${{{\rm { n}}}_{{\rm { D}}}^{{\rm { 20}}}}$ is a measure of the overall oscillator strength of the electronic transitions, that is, it is proportional to the number of C atoms. In addition, the position of the OH group also seems to be characteristic [1,3,23–25] . Thus, the decrease of normalnD20 ${{{\rm { n}}}_{{\rm { D}}}^{{\rm { 20}}}}$ as a function of N is more pronounced for tertiary alcohols than for primary or secondary ones indicating a higher oscillator strength and/or a stronger coupling of the solvent oscillators with those of the solute and consequently a stronger redshift in accordance with the previous study [8a] .…”
Section: Resultssupporting
confidence: 87%
“…It is assumed that the effective D HBD values for secondary and tertiary alcohols are lower than for the primary alcohols by a certain factor because of their different liquid structures. [ 1 , 3 , 23 , 24 , 25 ] It is predicted that a hypothetical factor f , that determines the efficiency of OH dipolar group action, depends on their position along the alkyl chain according to Ref. [1] We have assumed that this is the case and simply calculated the factor f for several monohydric secondary and tertiary as well as polyhydric alcohols from the deviation of the excellent linear relationship given by Equation (5).…”
Section: Resultsmentioning
confidence: 99%
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