Encyclopedia of Inorganic and Bioinorganic Chemistry 2024
DOI: 10.1002/9781119951438.eibc2882
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An Introduction to the Chemistry and Properties of Excited‐State Mixed‐Valence Systems

Ivana Ramírez‐Wierzbicki,
Agustina Cotic,
Alejandro Cadranel

Abstract: While ground‐state mixed‐valence systems are very well known, excited‐state mixed‐valence (ES‐MV) systems received comparably less attention. Intervalence charge‐transfer (IVCT) excited states, locally excited mixed‐valence (LE‐MV) systems, and photoinduced mixed‐valence (PI‐MV) systems are different types of ES‐MV systems. They are the simplest models for excited‐state electron transfer reactions, and therefore crucial in the development of solar energy conversion schemes. IVCT exited states are the best‐know… Show more

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