The adsorbate structural properties such as the type, number, and position of substituents on benzene ring of organic compound, as well as a length and arrangement of hydrocarbon chain in a space, exert a significant influence on the adsorption process. The measurements of adsorption equilibria and kinetics of several pesticides belonging to the group of halogenated phenoxyacids differentiated in terms of structural and physicochemical properties were studied in order to characterize the adsorption mechanism and correlate it with the pollutant properties. Regarding a complexity of investigations (capacity and rate) comprising 21 structurally closely related active substances showing the carcinogenic activity on living organisms and relatively long half-life time in the environment, the proposed intensive studies on the removal of pollutants by adsorption process are very important in cognitive and practical terms.