“…31 According to classic Flory−Huggins theory prediction, as the average molecular weight of a polymer decreases, the free volume of its chains increases, resulting in a lower physical entanglement in the polymer network. 32 Therefore, the elastic modulus can be reduced by decreasing its average molecular weight. In traditional polyurethanes (PU), chain extenders are used to increase the average molecular weight of the polymer or to increase the cross-linked density in the polymer network.…”