There is no doubt that the fourth-order King’s family is one of the important ones among its counterparts. However, it has two major problems: the first one is the calculation of the first-order derivative; secondly, it has a linear order of convergence in the case of multiple roots. In order to improve these complications, we suggested a new King’s family of iterative methods. The main features of our scheme are the optimal convergence order, being free from derivatives, and working for multiple roots (m≥2). In addition, we proposed a main theorem that illustrated the fourth order of convergence. It also satisfied the optimal Kung–Traub conjecture of iterative methods without memory. We compared our scheme with the latest iterative methods of the same order of convergence on several real-life problems. In accordance with the computational results, we concluded that our method showed superior behavior compared to the existing methods.