Tar balls are atmospheric
particles that are abundant in slightly
aged biomass burning smoke and have a significant, but highly uncertain,
role in Earth’s radiative balance. Tar balls are typically
detected using electron microscopy and generally, they are observed
as individual spheres. Here, we report new observations of a significant
fraction of tar ball aggregates (∼27% by number) from samples
collected in a plume of the Whitewater-Baldy Complex fire in New Mexico.
The structure of these aggregates is fractal-like and follows a scale
invariant power law similar to that of soot particles, despite the
considerably larger size and smaller number of monomers. We also present
observations of tar ball aggregates from four other geographical locations,
including a remote high-elevation site in the North Atlantic Ocean.
Aggregation affects the particle optical properties and, therefore,
their climatic impact. We performed numerical simulations based on
the observed morphology and estimated the effects of aggregation on
the optical properties of the tar balls. On the basis of single-particle
numerical simulations, we find that aggregates had a single scattering
albedo up to 41% and 23% higher than that of individual tar balls
at 550 nm and 350 nm, respectively.