Avantium is in the
process of building a flagship plant for the
production of furandicarboxylic acid (FDCA) and the derived polyester
polyethylene furanoate (PEF) using their YXY process. Because of the status of this development
of monomer production, next to storage and shipping, polymer production,
application development, and polymer recycling, the understanding
of the safety aspects of the YXY process is key for a successful deployment
of the technology. In this paper, the focus is on fire propagation-related
issues for both monomeric furanic compounds and for the polymer PEF
and results are compared with relevant reference materials. The current
assessment addresses the fire initiation and propagation behavior
of FDCA and PEF for the very first time. From the fire safety viewpoint,
it can be concluded that of the furanics tested, FDCA has a better
safety margin both in terms of a lower thermal and chemical threat,
as fires resulting from FDCA are not easily shifting toward underventilated
fire scenarios. The obtained results with the PEF polymer are useful
in understanding the nature and behavior of PEF under real fire conditions.
PEF seems slightly better in terms of the total energy released from
the combustion process than the bulk polyester PET. In addition, PEF
fires result in lesser CO and soot yields compared to PET, which is
proof for a better completeness of combustion.