An overview of the research and development of solid polymer electrolyte batteries

Murata, K.; Izuchi, Shuichi; Yoshihisa, Youetsu

doi:10.1016/s0013-4686(99)00365-5

Cited by 381 publications

(203 citation statements)

References 14 publications

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“…Several extensive reviews give a more detailed description of the different types of polymer electrolytes and their development. [125][126][127] Polymer electrolyte fi lms can be produced using various methods. It was reported that electrolyte fi lms could, for example, be prepared by casting from a polymer solution, [ 128 ] evaporation methods, [ 129 ] or in situ plasma polymerization techniques.…”

Section: Polymer Electrolytesmentioning

confidence: 99%

“…[ 130 ] The fi rst dry solid-state electrolytes had an ionic conductivity of approximately 10 − 7 S ⋅ cm − 1 . [ 127 ] It was discovered that ionic conductivity is mostly taking place in the amorphous zones of the polymer, so deposition methods that prevent crystallization improve the ionic conductivity. These methods may involve the addition of large side-groups to the polymer chains, crosslinking and the addition of plasticizers to keep the polymer chains mobile.…”

Section: Polymer Electrolytesmentioning

confidence: 99%

“…[ 125 , 126 ] Using these improvements, the ionic conductivity could be increased by several orders of magnitude up to 10 − 3 -10 − 4 S ⋅ cm − 1 . [ 127 ] …”

Section: Polymer Electrolytesmentioning

confidence: 99%

See 2 more Smart Citations

All‐Solid‐State Lithium‐Ion Microbatteries: A Review of Various Three‐Dimensional Concepts

Oudenhoven

Baggetto

Notten

2010

Advanced Energy Materials

699

638

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With the increasing importance of wireless microelectronic devices the need for on-board power supplies is evidently also increasing. Possible candidates for microenergy storage devices are planar all-solid-state Li-ion microbatteries, which are currently under development by several start-up companies. However, to increase the energy density of these microbatteries further and to ensure a high power delivery, three-dimensional (3D) designs are essential. Therefore, several concepts have been proposed for the design of 3D microbatteries and these are reviewed. In addition, an overview is given of the various electrode and electrolyte materials that are suitable for 3D all-solidstate microbatteries. Furthermore, methods are presented to produce fi lms of these materials on a nano-and microscale.www.MaterialsViews.com REVIEW www.advenergymat.de

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Section: Polymer Electrolytesmentioning

confidence: 99%

Section: Polymer Electrolytesmentioning

confidence: 99%

See 1 more Smart Citation

All‐Solid‐State Lithium‐Ion Microbatteries: A Review of Various Three‐Dimensional Concepts

Oudenhoven

Baggetto

Notten

2010

Advanced Energy Materials

699

638

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“…Electrolyte is an important component of electronic devices, which became the main focus of the research on the application of electrochemical devices [1] due to the establishment of ionic conductivity-performance correlation in a poly (ethylene oxide) (PEO)/Na + SPE system in 1973 [2]. Polymer electrolytes are grouped into three classes, namely solid, liquid, and gel.…”

Section: Introductionmentioning

confidence: 99%

A Study on Dielectric Properties of The Cellulose Derivative-NH4Br-Glycerol- Based The Solid Polymer Electrolyte System

Rasali

Muzakir

Samsudin

2017

MST

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The characterization of biopolymer-based solid polymer electrolytes (SPEs) has been carried out in this present work. Cellulose derivative was chosen due to its superior physical attributes. In this work, NH 4 Br-doped glycerol plasticized carboxyl methylcellulose-based SPEs were successfully prepared via the solution casting method. The conductivity and dielectric properties of the prepared films were investigated using the impedance analysis which presented ~1.91×10 -3 Scm -1 (with addition of 6 wt% of glycerol). In addition, the studied SPE system shows a non-Debye behaviour without a single relaxation time. The findings of the research indicate that the complexes of NH 4 Br and glycerol in the cellulose derivative influence the ionic conductivity and dielectric properties of the SPE system. AbstrakKajian Sifat Dialektik dari Gliserol Turunan Selulosa-NH4Br-Berdasarkan Sistem SPEs. Perkembangan elektrolit polimer pepejal (SPEs) berdasarkan bahan bio-polimer telah dilakukan dalam kajian sekarang ini. Bio-polimer dari turunan selulosa dipilih karena sifatnya yang unggul. Dalam karya sekarang ini, SPEs berdasarkan karboksil metilselulosa didopkan dengan NH 4 Br dan terplastikkan dengan gliserol telah berhasil disiapkan melalui metode tebaran larutan. Sifat unggul film telah diselidiki dalam terma konduktivitas mereka dan juga sifat dielektrik menggunakan teknik impedansi. Nilai ionik tertinggi untuk nilai konduktivitas yang ditemui ialah 1,91 × 10 -3 S cm -1 ketika 6 wt.% gliserol ditambahkan. Sifat dilektrik dari sistem SPEs menunjukkan tren yang signifikan di mana sistem ini secara tepatnya dapat disebut perilaku non-Debye tanpa waktu relaksasi tunggal. Interaksi dari NH 4 Br dan gliserol dalam turunan selulosa telah menunjukkan bahawa ianya mempengaruhi konduktivitas ionik dan sifat dielektrik dalam sistem SPEs.

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“…7,8 The technological implications of these electrolytes, with respect to their use in lithium ion batteries and supercapacitors were suggested and realized by many researchers. 4,5 However, PEO containing alkali metal ions still exhibit relatively low ionic conductivity 9 to that of liquid/aqueous electrolytes.…”

Section: Introductionmentioning

confidence: 99%

PEO nanocomposite polymer electrolyte for solid state symmetric capacitors

Singh¹,

Verma

Minakshi

2015

Bull Mater Sci

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Abstract. Physical and electrochemical properties of polyethylene oxide (PEO)-based nanocomposite solid polymer electrolytes (NPEs) were investigated for symmetric capacitor applications. Nanosize fillers, i.e., Al 2 O 3 and SiO 2 incorporated polymer electrolyte exhibited higher ionic conductivity than those with filler-free composites. The composites have been synthesized by the completely dry (solution-free) hot-press method. The addition of filler in fractional amount to the solid polymer matrix at room temperature further enhances the ionic conductivity. Nature of the NPEs were studied using X-ray diffraction and energy-dispersive spectra analyses.

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An overview of the research and development of solid polymer electrolyte batteries

Cited by 381 publications

References 14 publications

All‐Solid‐State Lithium‐Ion Microbatteries: A Review of Various Three‐Dimensional Concepts

All‐Solid‐State Lithium‐Ion Microbatteries: A Review of Various Three‐Dimensional Concepts

A Study on Dielectric Properties of The Cellulose Derivative-NH4Br-Glycerol- Based The Solid Polymer Electrolyte System

PEO nanocomposite polymer electrolyte for solid state symmetric capacitors

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