“…Hence, it is important to rationally couple the α-Fe 2 O 3 nanoleaves with other nanomaterials to form a novel hybrid structure which can reveal enhanced electrochemical activity. There have been recent reports on hybrid α-Fe 2 O 3 composites such as graphene oxide-α-Fe 2 O 3 , MWCNT-α-Fe 2 O 3 , chitosan-α-Fe 2 O 3 -terephthalaldehyde, and carbon nitride-α-Fe 2 O 3 used for electrochemical sensing of hydroquinone, ascorbic acid, DNA, and glucose, respectively. − Meanwhile, reduced graphene oxide-Fe 2 O 3 , N -RGO-Fe 2 O 3 , and single-crystalline Fe 2 O 3 particles/graphene modified composites were reported for supercapacitor applications. − To the best of our knowledge, this is the first report on an α-Fe 2 O 3 nanoleaf-decorated MPC-chit modified composite for two different potential applications: selective electrochemical sensing of nitrite at neutral pH and high-performance supercapacitor applications at alkaline pH. Recently, mesoporous carbon has attracted much attention as a host material for metals, metal oxides, and polymers for electrochemical sensors and energy storage applications. − The high surface area, good electrical conductivity, a well-defined, large pore volume, and the unique features resulting from combining biopolymer chitosan enable higher α-Fe 2 O 3 nanoleaf incorporation for improved electrocatalytic activity of nitrite and supercapacitor applications.…”