An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues

Ma, Huirong; Liu, Liangchen; Liao, Yuluan; Shi, Huatian; Sun, Po; Yu, Weibin

doi:10.1039/d4qi00343h

Inorg. Chem. Front.

2024

DOI: 10.1039/d4qi00343h

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An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues

Huirong Ma,

Liangchen Liu,

Yuluan Liao

et al.

Abstract: The direct decomposition of nitromethane into nitrile compounds poses a significant challenge due to the occurrence of severe side reactions. In this study, we present a novel and gentle methodology...

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Cited by 2 publications

References 79 publications

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Using Rigidity and Conjugation of Subunits to Modulate Supramolecular Topologies Constructed by Half‐Sandwich Fragments

Liu,

Liao,

et al. 2024

Chemistry An Asian Journal

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The synthesis of supramolecular compounds with a high degree of controllability and the targeted modulation of their topological transitions pose significant challenges in situ. In this study, we have successfully constructed an array of discrete structures based on a series of bidentate pyridyl ligands (L1, L2, and L3), which were subsequently ligated with half‐sandwiched (Cp*Ir fragments) building blocks. Our further investigations elucidate a strategy for coordinating the relative lengths of the bidentate ligands with the building blocks, achieving specific concentrations that drive the transformation of tetranuclear metal macrocycles into Borromean rings. Notably, the distinct characteristics of the three pyridyl ligands markedly influence the efficiency of synthesis and the topological conversion of the supramolecular macrocycles. Detailed structural analyses reveal that π‐π stacking interactions, the electron‐donating capabilities of the ligands, and hydrogen‐bonding interactions are pivotal in stabilizing these molecular macrocycles and in facilitating their transformation to Borromean rings. The analyses underscore the importance of the electron‐rich effect induced by the sulfur atoms in the ligands and the regulation and modulation of the pyridine functional group in contributing to the structural stability and altered characteristics of the macrocycles.

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Using Rigidity and Conjugation of Subunits to Modulate Supramolecular Topologies Constructed by Half‐Sandwich Fragments

Liu,

Liao,

et al. 2024

Chemistry An Asian Journal

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Selective construction and effective photothermal conversion of octanuclear metallacage and dinuclear metallatriangle based on the tetraphenylethylene unit

Zheng,

Wang,

Yuan

et al. 2024

Journal of Solid State Chemistry

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An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues

Abstract: The direct decomposition of nitromethane into nitrile compounds poses a significant challenge due to the occurrence of severe side reactions. In this study, we present a novel and gentle methodology...

Cited by 2 publications

References 79 publications

Using Rigidity and Conjugation of Subunits to Modulate Supramolecular Topologies Constructed by Half‐Sandwich Fragments

Using Rigidity and Conjugation of Subunits to Modulate Supramolecular Topologies Constructed by Half‐Sandwich Fragments

Selective construction and effective photothermal conversion of octanuclear metallacage and dinuclear metallatriangle based on the tetraphenylethylene unit

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