“…During the last period with a HRT of 7 h and VLRs above 4 kg COD/m 3 d, a continuous increase in the tCOD of the effluent was observed, reaching effluent tCOD values of 125-250 mg O 2 /L and effluent BOD 5 of 40-125 mg O 2 /L at The mean value of total VFA in the effluent at a VLR of 2-2.5 kg COD/m 3 d was 21.2 ± 14.6 mg/L (composed of acetic, propionic, butyric acid at 68.5 ± 48.4%, 15.2 ± 9.5%, and 16.3 ± 11.1%, respectively). VLRs of 3.5-4.5 kg COD/m 3 d resulted in an increase of VFA, with effluent VFA concentrations of 47.2 ± 33.4 mg/L.The results obtained confirmed that AnMBR treating municipal wastewater at psychrophilic temperature (18 ± 2ºC) achieved effluent tCOD values below the legal discharge limit at HRT of 7-10 h and VLRs of 2.5 kg tCOD/m 3 d. Similar tCOD removal efficiencies were obtained byMartinez-Sosa et al, (2012), working at 20 ± 1ºC Kg COD/m 3 d and an HRT of 16 h when working with synthetic wastewater, however with municipal wastewater the COD removal efficiency averaged 69 % ± 10% Gao et al, ( 2014),. working with municipal wastewater at three temperatures (35ºC, 25ºC and 15ºC) with volumetric loading rates between 1.2-1.44 g COD/L d and a HRT of 6 h, reported a decrease in COD removal efficiency in correspondence with temperature, ranging from 74% to 67% and 51% respectively.…”