Durability degradation in reinforced concrete (RC) constructions is commonly attributed to the steel reinforcement corrosion caused by chloride. The utilization of supplemental cementitious resources, such as waste materials from industrial and agricultural sectors, typically improves the impermeability and strengthens concrete resistance to corrosion, sulfate, and acid attacks. Therefore, the prevention of steel reinforcement corrosion is greatly important in resolving challenges related to the durability and stability of RC structures, particularly when utilizing agriculture waste materials. This approach also serves as a solution for waste disposal. The aim of this study is to investigate the corrosion-resistant characteristics of high-strength concrete that contains ultrafine palm oil fuel ash (U-POFA) as a partial replacement for cement. Four high-strength green concrete (HSGC) mixes were investigated in this study with a partial replacement of ordinary Portland cement (OPC) by U-POFA at 0, 20, 40, and 60% by mass. The aim of this study is to analyze the workability, strength activity index (SAI), compressive strength, rapid chloride permeability, linear polarization resistance (LPR) by different measurement methods, and four-probe resistivity measurement by electrical resistivity measurement method of over a curing period of 7, 28, 60, and 90 days. The use of U-POFA in the different mixes results in improved workability, SAI, compression strength, and chloride penetration resistance compared with the zero-POFA mix. It is clear from the study results that adding U-POFA as a partial replacement for OPC improved the corrosion resistance of HSGC mixtures. Thus, the incorporation of U-POFA 60% succeeded in reducing the chloride ion penetration by 80% and the LPR by 93% at the test age of 90 days, compared to the reference mixture.