This manuscript presents a comprehensive exploration of the band gap structure of (CoCrFeNiMn)3O4 powders through a series of experimental investigations. The combined use of optical techniques and X-ray photoelectron spectroscopy in this study leads to a comprehensive characterization of the band gap structure in (CoCrFeNiMn)3O4 powders. The findings contribute to the understanding of this material’s electronic properties and pave the way for potential applications in electronic and optical devices.