Analysis of 5-chloro-8-methoxy-2-(bromomethyl)quinoline by XPS

Abstract

Macrocyclic ethers are used extensively for their ability to form strong and selective interactions with charged species. It has been shown that the incorporation of heterocyclic groups into macrocylclic ethers increase rigidity and interaction with certain ions. Alkylation of these azacrowns with benzylic halides can attach fluorionophoric substituents onto the ring. One of the molecules used for this alkylation is 5-chloro-8-methoxy-2-͑bromomethyl͒quinoline. Azacrowns with this alkyl ligand have displayed interesting ion complexation properties.

Thiophene or Pyridine-Substituted Quinoline Derivatives: Synthesis, Properties, and Electropolymerization for Energy Storage

“…Figure 6 shows the XPS results of the PTh-Q. In Figure 6(a), the deconvoluted C 1 s peaks at 284.50 eV, 285.12 eV, and 287.18 eV are originated from the C-C or C=C, C-S, and C-O structures, respectively [30,31]. The N 1 s peak (Figure 6(b)) can be deconvoluted into peaks at 400.22 eV and 401.45 eV that correspond to the C-N in the quinoline ring and oxidized N, respectively [30,31].…”

“…In Figure 6(a), the deconvoluted C 1 s peaks at 284.50 eV, 285.12 eV, and 287.18 eV are originated from the C-C or C=C, C-S, and C-O structures, respectively [30,31]. The N 1 s peak (Figure 6(b)) can be deconvoluted into peaks at 400.22 eV and 401.45 eV that correspond to the C-N in the quinoline ring and oxidized N, respectively [30,31]. 9 International Journal of Energy Research Moreover, the O 1 s peak shown in Figure 6(c) can be deconvoluted into the peaks at 532.54 eV (O-H structure) and 533.37 eV (C-O structure) [30,31].…”

“…The N 1 s peak (Figure 6(b)) can be deconvoluted into peaks at 400.22 eV and 401.45 eV that correspond to the C-N in the quinoline ring and oxidized N, respectively [30,31]. 9 International Journal of Energy Research Moreover, the O 1 s peak shown in Figure 6(c) can be deconvoluted into the peaks at 532.54 eV (O-H structure) and 533.37 eV (C-O structure) [30,31]. In Figure 6(d), the deconvoluted S 2 p peaks match the thiophene structure (164.49 eV and 166.21 eV) and the S-O bond (168.81 eV and 169.79 eV) [32][33][34].…”