As a Pacific Island, Hawaiʻi's hydrological processes are influenced by strong spatio-temporal gradients in, and close interactions between, rainfall, land-use, near-surface geological conditions, and complicated subsurface hydrogeology. Due to their volcanic nature, the hydrogeology of Hawaiʻi predominantly consists of basaltic bedrock formations that vary in terms of, for example, the type of lava flow deposit ('A'ā vs. Pāhoehoe), age, and thickness of individual flow units. Several factors, such as the age of the islands and climatic variability, control regolith development, and its characteristics (Ryu et al., 2014;P. Vitousek, 2004).Hawaiian hydrogeology possesses strong spatio-temporal gradients and heterogeneity at a variety of spatial scales (Figure 1). For example, basaltic formations are dominated by both small-and intermediate-scale fractures and large-scale faults that strongly affect chemical fate and transport processes (Deng & Spycher, 2019). Mechanical weathering and chemical alteration create saprolite layers with low hydraulic conductivity, forming barriers to flow (Figure 1) and/or causing groundwater to be trapped in perched formations (Hunt, 1996;Mink & Lau, 1980;Oki, 2005). On the island of Oʻahu, as well as on other Pacific islands, valley-ridge complexes are known to generate highly complicated groundwater systems (Oki, 2005). Older alluvium deposits, created during periods of extensive erosion that carved deep valleys in the original volcanoes, are of hydrological importance due to their relatively low hydraulic conductivity, estimated to be in the range of 3.96 × 10 −3 m/day (0.013 ft/day) to 0.33 m/day (1.08 ft/day) (Wentworth, 1938). The low permeability is related to chemical alteration, weathering, and compaction (Oki, 2005;Wentworth, 1951).