Endothermic
hydrocarbon fuels (EHFs) are meant to regeneratively
cool high-speed flight components and surfaces. In addition to physical
heat absorption, they also undergo thermal decomposition thus offering
a chemical heat sink. In this study, two single-molecule hydrocarbons,
i.e., JP-10 (exotetrahydrodicyclopentadiene) and 3-carene (3,7,7-trimethylbicyclo[4.1.0]hept-3-ene),
are tested for their applicability as EHF. Noncatalytic and catalytic
pyrolysis tests were carried out in an analytical Curie point pyrolyzer
coupled with gas chromatograph/mass spectrometer using zeolites (HY,
Hβ, and Mordenite) at 500 and 650 °C. A quantitative analysis
of the pyrolysate composition is performed to evaluate the effects
of temperature, catalyst type and catalyst loading. The results demonstrated
that the effect of temperature was minimal since the pyrolytic reactions
were driven primarily by the protolysis of the reactants. The yields
of low molecular weight (LMW) hydrocarbons were higher with HY and
Hβ, whereas the extent of cracking was low over Mordenite. The
highest LMW alkene and alkane yields of 11.9 and 5.8 wt %, respectively,
were achieved with HY in the case of JP-10. Similarly, for 3-carene,
LMW alkene and alkane yields were 15.2 and 11.4 wt %, respectively,
in the presence of HY. Propylene, isobutylene and isopentane were
the dominant pyrolysates from both the fuels with catalysts. Cycloalkanes
and cycloalkenes were the major alicyclic hydrocarbons formed from
JP-10 and 3-carene, respectively. The yields of alkanes, alkenes,
cycloalkanes and benzene derivatives increased with catalyst loading
for JP-10. In the case of 3-carene, a similar trend was followed except
for cycloalkenes whose yield decreased with catalyst loading. Plausible
reaction pathways for the formation of LMW hydrocarbons from both
the fuels are proposed.