Analysis of electrocatalytic processes with following electron transfer by a potential step method.  Theory and application to the phenanthrene-octyl chloride system

Britton, Wayne E.; Fry, Albert J.

doi:10.1021/ac60351a015

Cited by 21 publications

(1 citation statement)

References 16 publications

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“…Other early investigations involved the catalytic reduction of 1-bromo-and 1-chlorobutane by the anion radicals of trans-stilbene and anthracene [132], of 1-chlorohexane and 6-chloro-1-hexene by the naphthalene anion radical [133], and of 1-chlorooctane by the phenanthrene anion radical [134]. Simonet and coworkers [135] pointed out that a catalytically formed alkyl radical can react with an aromatic anion radical to form an alkylated aromatic hydrocarbon.…”

Section: Catalytic Reduction Of Carbon-halogen Bondsmentioning

confidence: 99%

Oxidation and Reduction of Halogen‐containing Compounds

Peters

2004

Encyclopedia of Electrochemistry

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The sections in this article are Introduction Anodic Processes Halogenated Alkanes Alicyclic Halides Aryl Halides Cathodic Processes Halogenated Alkanes Halogenated Alkenes and Alkynes Benzyl Halides Alicyclic Halides Aryl Halides Acyl and Phenacyl Halides Aliphatic α‐Halocarbonyl Compounds Halogenated Heterocyclic Compounds Catalytic Reduction of Carbon–Halogen Bonds

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Section: Catalytic Reduction Of Carbon-halogen Bondsmentioning

confidence: 99%

Oxidation and Reduction of Halogen‐containing Compounds

Peters

2004

Encyclopedia of Electrochemistry

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Elektro-Deblockierung — Elektrochemische Abspaltung von Schutzgruppen

Mairanovsky¹

1976

Angew. Chem.

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Viele Schutzgruppen lassen sich durch elektrochemische Reaktionen entfernen. In diesem Aufsatz werden theoretische und präparative Aspekte der Methode anhand von Beispielen diskutiert. Die Abspaltung erfordert oft hohe Potentiale. Durch Verwendung modifizierter Schutzgruppen („innere Aktivierung”︁) oder durch Zusatz von Katalysatoren (Elektronenüberträgern), die den Elektronenübergang entgegen dem Standardpotential‐Gradienten ermöglichen („äußere Aktivierung”︁), kann der Anwendungsbereich der elektrochemischen Methode erweitert werden.

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Electro‐Deprotection—Electrochemical Removal of Protecting Groups

Mairanovsky¹

1976

Angew. Chem. Int. Ed. Engl.

142

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The reactions of electrochemical splitting may be successfully used for removal of protecting groups. Theoretical and preparative aspects of the method of electro‐deprotection are discussed, and examples of its use are given. The removal often requires high potentials. The use of modified protecting groups (“inner activation”) or of catalysts (electron carriers) which facilitate electron transfer against the standard potential gradient (“external activation”), can greatly increase the scope of the electrochemical method.

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Analysis of electrocatalytic processes with following electron transfer by a potential step method. Theory and application to the phenanthrene-octyl chloride system

Abstract: Meeting of The Electrochemical Society in Washington, D.C., May 1971. Financial support was provided by the National Science Foundation. The Wesleyan University Computing Center provided computer time.

Cited by 21 publications

References 16 publications

Oxidation and Reduction of Halogen‐containing Compounds

Oxidation and Reduction of Halogen‐containing Compounds

Elektro-Deblockierung — Elektrochemische Abspaltung von Schutzgruppen

Electro‐Deprotection—Electrochemical Removal of Protecting Groups

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