Analysis of Electrochemical Noise for Type 410 Stainless Steel in Chloride Solutions

Kelly, R. G.; Inman, ME; Hudson, J. L.

doi:10.1520/stp37954s

Cited by 26 publications

(22 citation statements)

References 10 publications

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“…3 showed the plotting of the evaluations of this ratio, R n , and the corrosion rate in ranking order of corrosion rate from the samples of steel-reinforced concrete immersed in the corrosive testmedium in the study. This figure generally showed that the sample with the higher-valued R n was attended with low corrosion rate, while the sample with the lower-valued R n exhibited high corrosion rate, which finds agreement with Kelly et al [38] where R n values tracked linear polarisation resistance. These forms of results engender suggestions of the existence of relationship between the experimental data of corrosion rate and the noise resistance.…”

Section: Correlation Fittings and Analysis Of Corrosion Rate And Noissupporting

confidence: 89%

“…Noise resistance (R n ) modelling Requisite estimations, from the descriptive statistics exhibiting better compatibility with the scatter of the HCP and the ECC test-data were used for the ratio of the standard deviations of the corrosion potential and corrosion current, the noise resistance (R n ) as [26][27]31,[38][39]:…”

Section: Statistical Analysis Of Measured Corrosion Test-datamentioning

confidence: 99%

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Electrochemical Performance of Phyllanthus Muellerianus on the Corrosion of Concrete Steel-reinforcement in Industrial/Microbial Simulating-environment

Okeniyi¹,

Loto²,

Popoola³

2014

Port. Electrochim. Acta

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Electrochemical monitoring techniques were employed in this study to assess anticorrosion performance of Phyllanthus muellerianus leaf-extract on concrete steelreinforcement in 0.5 M H 2 SO 4 , used for simulating industrial/microbial environment. For this, steel-reinforced concretes admixed with different concentrations of the natural plant leaf-extract were partially immersed in the acidic test-solution and subjected to electrochemical monitoring of corrosion potential, corrosion current and corrosion rate. Test responses analysed as per ASTM G16-95 R04, showed that the corrosion rate correlated, r = 84.93%, ANOVA p-value = 0.0403, with the leaf-extract concentration admixed in concrete and the ratio of the standard deviation of potential to the standard deviation of current. These identified the 0.3333% Phyllanthus muellerianus (per weight of cement) with optimum effectiveness at inhibiting steel-reinforcement corrosion both by the experimental model, η = 91.66±2.51%, and by the prediction from the correlation fitting model, η = 85.54±14.44%. Fittings of both the experimental and the predicted data followed the Flory-Huggins and the Frumkin adsorption isotherms which suggest prevalent mechanism of physical adsorption (physisorption) of the extract on steel-rebar surface. These support the use of Phyllanthus muellerianus as environmentally-friendly admixture for inhibiting concrete steel-reinforcement corrosion in the industrial/microbial service-environment.

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Section: Correlation Fittings and Analysis Of Corrosion Rate And Noissupporting

confidence: 89%

Section: Statistical Analysis Of Measured Corrosion Test-datamentioning

confidence: 99%

Electrochemical Performance of Phyllanthus Muellerianus on the Corrosion of Concrete Steel-reinforcement in Industrial/Microbial Simulating-environment

Okeniyi¹,

Loto²,

Popoola³

2014

Port. Electrochim. Acta

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“…As could be observed in Figure 3, studies have shown that the corrosion noise resistance is generally high-valued at low corrosion rate and low-valued at high corrosion rate due to the fact that the corrosion noise resistance tracks the linear polarization resistance [36,56,59,60]. This relationship of corrosion noise resistance with corrosion rate, and vice versa, had been employed for detailing correlation expressions between these corrosion variables in reported works [36,56,60].…”

Section: Corrosion Rate and Corrosion Noise Resistance For Correlatiomentioning

confidence: 99%

“…Measurements of dispersion from the descriptive statistics that exhibited better compatibility with the scatter of the corrosion-potential and the corrosion-current test-data were used for modeling the corrosion noise-resistance [56,58,59]. This noise-resistance was modeled as the ratio of standard deviation of corrosion-potential (CP) to the standard deviation of corrosion-current (CC), using the formula in Equation (7):…”

Section: Initiation Of Corrosion Test-data Analyses-statistical Distrmentioning

confidence: 99%

Effects of Phyllanthus muellerianus Leaf-Extract on Steel-Reinforcement Corrosion in 3.5% NaCl-Immersed Concrete

Okeniyi

Loto

Popoola

2016

Metals

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This paper investigates Phyllanthus muellerianus leaf-extract effects on steel-reinforcement corrosion in concrete immersed in 3.5% NaCl, simulating saline/marine environment. Different concentrations of the leaf-extract were admixed in steel-reinforced concrete samples, which were immersed, with normal control, in the test-environment, while positive control samples were immersed in distilled water. Electrochemical measurements of corrosion-rate (by linear-polarizationresistance instrument), corrosion-current (by zero-resistance-ammeter) and corrosion-potential (by high impedance multimeter) were obtained for assessing the reinforcing-steel corrosion. Analyzed results showed that the corrosion-rate exhibited excellent correlation (R = 98.82%, Nash-Sutcliffe Efficiency = 97.66%, ANOVA p-value = 0.0006) with function of the admixture concentration and of the corrosion noise-resistance (ratio of corrosion-potential and corrosion-current standard deviations). The 0.3333% Phyllanthus muellerianus (per weight of cement) exhibited optimal efficiency, η = 97.58% ± 1.28% (experimental) or 95.33% ± 4.25% (predicted), at inhibiting concrete steel-reinforcement corrosion in the test-environment, which compares well with the positive control performance model, η = 97.96% ± 0.03%. The experimental and predicted models followed the Langmuir adsorption isotherm, which indicated physisorption as the Phyllanthus muellerianus leaf-extract adsorption mechanism on the reinforcing-steel. These support suitability of the N-, S-, and O-containing and π-electron rich Phyllanthus muellerianus leaf-extract as an environmentally-friendly inhibitor for effective corrosion-protection of steel-reinforcement in concrete designed for the saline/marine environment.

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“…Así, los métodos estadísticos se centran, fundamentalmente, en el estudio de la evolución en el tiempo de la desviación estándar de las señales de densidad de corriente, G¡, y de potencial, G E . La resistencia de ruido, R n , definida como el cociente o E lo v se ha relacionado con la resistencia de polarización, R p , y se ha discutido su validez para evaluar la velocidad de corrosión (2)(3)(4)(5).…”

Section: Introductionunclassified

Seguimiento de la corrosión de la aleación AA2024 en disoluciones de NaCl mediante la medida del ruido electroquímico

Aballe¹,

Bethencourt²,

Botana³

et al. 1998

REVMETAL

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Resumen Se ha realizado un seguimiento del comportamiento frente a la corrosión de la aleación AA2024 en disolución acuosa de NaCl al 3,5 %, medio en el cual esta aleación es muy sensible a la acción de pequeñas polarizaciones anódicas. El estudio se ha llevado a cabo utilizando diferentes técnicas electroquímicas: polarización lineal (PL), espectroscopia de impedancia electroquímica (EIS) y medida del ruido electroquímico (ENM). Los datos obtenidos mediante esta última técnica se han analizado utilizando parámetros estadístiscos y conceptos relacionados con la Teoría del Caos. Los resultados obtenidos ponen de manifiesto que el registro de ruido electroquímico puede resultar de gran utilidad para el seguimiento de sistemas, como el aquí estudiado, susceptibles de ser modificados al aplicar otras técnicas electroquímicas.Palabras clave: AA2024. EIS. ENM. Caos.Corrosión monitoring of the AA2024 alloy in NaCl solutions by electrochemical noise meassurements AbstractThe behaviour of the AA2024 alloy against corrosión in 3.5 % NaCl solution has been monitored. In this environment the alloy can be easily damaged under small anodic polarizations. Linear polarization, electrochemical impedance, spectroscopy and electrochemical noise meassurement have been used as experimental techniques. Data from ENM have been analized using statistical parameters and Chaos Theory. The results here obtained suggest that ENM is particularly useful to monitore systems that can be modified using other electochemical techniques.Keywords: AA2024. EIS. ENM. Chaos. INTRODUCCIÓNLa técnica de ruido electroquímico (ENM) se basa en el estudio de las oscilaciones de corriente y potencial, en función del tiempo, que se producen cuando un metal se corroe libremente. El análisis de los resultados así obtenidos proporciona información relacionada con el proceso de corrosión que está teniendo lugar (1). En la bibliografía, se describen diferentes méto-dos para el análisis de los datos procedentes de ensayos de ENM. Así, los métodos estadísticos se centran, fundamentalmente, en el estudio de la evolución en el tiempo de la desviación estándar de las señales de densidad de corriente, G¡, y de potencial, G E . La resistencia de ruido, R n , definida como el cociente o E lo v se ha relacionado con la resistencia de polarización, R p , y se ha discutido su validez para evaluar la velocidad de corrosión (2-5).Una segunda tendencia en el análisis de los datos de ruido electroquímico se basa en el empleo de conceptos relacionados con la Teoría del Caos. El método del retardo en el tiempo permite reconstruir, en el espacio de las configuraciones, los posibles atraetores caóticos que controlan el proceso global. En (6) se propone que la distribución de los puntos

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Analysis of Electrochemical Noise for Type 410 Stainless Steel in Chloride Solutions

Cited by 26 publications

References 10 publications

Electrochemical Performance of Phyllanthus Muellerianus on the Corrosion of Concrete Steel-reinforcement in Industrial/Microbial Simulating-environment

Electrochemical Performance of Phyllanthus Muellerianus on the Corrosion of Concrete Steel-reinforcement in Industrial/Microbial Simulating-environment

Effects of Phyllanthus muellerianus Leaf-Extract on Steel-Reinforcement Corrosion in 3.5% NaCl-Immersed Concrete

Seguimiento de la corrosión de la aleación AA2024 en disoluciones de NaCl mediante la medida del ruido electroquímico

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