The article is devoted to the analysis of the internal structure and properties of a copper-graphite coating applied to a copper electrode. The article provides a calculation of the transient contact resistance of electrodes with a coating obtained using plasma spraying technology. Copper-graphite powder with high arc resistance was used as a spraying substance. Coated electrodes were tested for erosion resistance by an arc at currents of several kiloamperes. The aim of the work is to determine the effect of the composition and internal structure of the coating on the transient processes in the contact gap.