Nowadays, energy shortages and environmental pollution have received a lot of attention, which makes the electrification of transportation systems an inevitable trend. As the core part of an electrical driving system, the electrical machine faces the extreme challenge of keeping high power density and high efficiency output under complex workin g conditions. The development and research of new soft magnetic materials has an important impact to solve the current bottleneck problems of electrical machines. In this paper, the variation trend of magnetic properties of ultra-thin grain-oriented silicon steel electrical steel (GOES) under thermal-mechanical-electric-magnetic fields is studied, and the possibility of its application in motors is explored. The magnetic properties of grain-oriented silicon steel samples under different conditions were measured by the Epstein frame method and self-built multi-physical field device. It is verified that the magnetic properties of grain-oriented silicon steel selected within 30° magnetization deviation angle are better than non-grain-oriented silicon steel. The magnetic properties of the same ultra-thin grain-oriented silicon steel as ordinary non-oriented silicon steel deteriorate with the increase in frequency. Different from conventional non-grain-oriented silicon steel, its magnetic properties will deteriorate with the increase in temperature. Under the stress of 30 Mpa, the magnetic properties of the grain-oriented silicon steel are the best; under the coupling of multiple physical fields, the change trend of magnetic properties of grain-oriented silicon steel is similar to that of single physical field, but the specific quantitative values are different. Furthermore, the application of grain-oriented silicon steel in interior permanent magnet synchronous motor (IPM) for electric vehicles is explored. Through a precise oriented silicon steel motor model, it is proved that the magnetic flux density of stator teeth increases by 2.2%, the electromagnetic torque of motor increases by 2.18%, and the peak efficiency increases by 1% after using grain-oriented silicon steel. In this paper, through the investigation of the characteristics of grain-oriented silicon steel, it is preliminarily verified that grain-oriented silicon steel has a great application prospect in the drive motor (IPM) of electric vehicles, and it is an effective means to break the bottleneck of current motor design.