This academic paper revolves around the results of research on the change in emission parameters of the used heating boiler following the introduction of the overheated water stream, which had an impact on different emission parameters. The research results provide an insight into the hard coal combustion process, which had a significant impact on the change in the chemical composition of exhaust gases: it contributed to the lower mass concentration of the emitted dust and black carbon (PM) as well as nitric oxides (NOx) while, at the same time, playing a significant role in increasing the mass concentration of the emitted carbon oxide (CO). Two types of devices were used for the purposes of conducting the research at hand: a boiler with an automatic fuel feeding system with one combustion chamber and a boiler with a combustion chamber and an afterburning chamber fitted over it. Apart from the measurements of mass concentration of the emitted harmful substances, the research also focused on measurements of temperature inside the combustion and afterburning chambers, as well as the temperature of exhaust gases and their oxygen content. As part of the research, water steam was introduced to the combustion and afterburning chambers at the flow rate of 0.71 kg/h and 3.60 kg/h for boilers operating at a minimum power of 30% and a nominal power of 100%. An original steam generator with an overheated water steam production range from 0.71 kg/h to 3.60 kg/h was used to create and feed the water steam. The efficiency of the combustion process was calculated using the obtained results for each operating configuration of a given boiler.