Practical application of microbial fuel cell (MFC), a sustainable energy
device, is hampered by low power output. Its principal components i.e.
anode, cathode and proton exchange membrane (PEM) are the focus of
enhancement and modification in terms of their functional design and
material. The anode surface conduciveness as electron sink is crucial to the
power output magnitude, while the cathode electrode should be reactive for
efficient oxygen reduction at tri-phase junction. PEM is solely responsible
for unidirectional proton flow concomitantly completing the electrical
circuit. Polymeric nanocomposites as electrode modifier improved
significantly anode/cathode/PEM functions thus overall MFC performance. The
review highlights the progress made in polymer-based modifications to anode,
cathode and PEM material and function between year 2014 to 2019. The effects
to biocompatibility, surface area, internal resistance, electrochemical
activities, environmental sustainability, and overall MFC performance are
discussed.