Additively manufactured metallic parts usually need postprocessing in order to achieve required shape accuracy. Cylindrical test specimens were produced by selective laser melting from Ti6Al4V powder material with different processing parameters. The aim of postprocessing was modification of shape accuracy. Sliding friction diamond burnishing was applied as the postprocessing method. A five-factor, two-level full factorial design of experiment was implemented with factors being infill laser power, infill laser scan speed, burnishing speed, feed and force. Improvement ratios of two roundness parameters were defined, calculated from experimental data, and studied by main effect and interaction analysis. It has been demonstrated that burnishing feed has the largest main effect to improvement in roundness total and cylindricity. Additionally, parameters of both selective laser melting and diamond burnishing appear in three largest interaction terms. Empirical functions were fit to measurement data. Results show that improvement in roundness parameters are strongly nonlinear functions of all factors.