The standard method for the detection and mapping of small particles on 200mm unpatterned wafers is light scattering. The standard approach to determining what these particles are, and their origin, is to re-find them in a full wafer SEM and rely on SEM/EDX for analysis. At very small particle sizes (below 0.2 microns) the light scattering location inaccuracies make it hard to re-locate the particles in SEM and EDX can have difficulty because it is not a small volume technique. In addition EDX often does not have enough characterization power to lead to a root cause determination. A number of 200mm analytical alternatives have become available since the first conference in this series two years ago. Between them they provide better small volume and surface sensitivity, plus chemical and molecular information. These are: other modes of optical microscopy combined with wafer marking, AFM, SAM, FIB, and TOF-SIMS. We have evaluated all these using real defect situations on full wafers. A review of their capabilities is given here. In addition we discuss micro-calorimetry based EDX and micro-ESCA/XANES, techniques not yet available in 200mm form.