The present paper completes a series of works on the influence on solar processes of fast charged particles produced in exoergic reactions in the solar core. The general picture of suprathermal effects triggered by the most energetic of them—MeV protons and α-particles—is composed. All reactions in the pp chain and the CNO cycle induced by these particles are examined. It is shown that some opposite suprathermal (p, α) and (α, p) reactions can be balanced, but their rates can exceed the rates of the respective thermal processes, affecting some points of nuclear fusion in the solar core. In particular, the suprathermal channels of p + 17O
α + 14N reactions increase the total energy released in these processes by a factor of 1.64, and enhance the mass fractions of 17O and 18O by ∼1–4 times at radii
. The same result is also obtained for the 18F abundance, leading to the proportional enhancement of the 18F neutrino emission rate. At the same time, integral characteristics like the total energy production and neutrino generation in the solar core remain unchanged.