Shear tests on quartz rocks and single quartz crystals have been conducted to understand the possible relationship between the intensity of detectable stress in fault areas and the energy released in the form of electromagnetic waves in the range 30 KHz-1 MHz (LF–MF). For these tests, a new type of piston-cylinder has been developed, instrumented to collect the electromagnetic signals generated by the quartz during shear stress tests and that allows energy measurements on electromagnetic emissions (EMR) to be performed. The data obtained indicate that shear-stressed quartz crystals can generate electromagnetic emissions in the LF–MF range. These emissions represent a tiny fraction of the total energy dissipated in the fracturing process. The spectrum of radio emissions consists of continuous radiation and overlapping peaks. For the first time, a characteristic migration of peak frequencies was observed, proportional to the evolution of the fracturing process. In particular, the continuous recording of the radio emission spectra shows a migration of the peaks toward higher frequencies, as stress continues over time and smaller and larger fractures form. This migration could be used to distinguish possible natural signals emitted by quartz in tectonically active environments from possible signals of other geophysical and possibly anthropogenic origin.