Analysis of Ternary Mixtures Containing Nonconsolute Components

Abstract

chlorine and then rises rapidly for chlorine contents above 35%. LITERATURE CITEDThis rise is undoubtedly associated with the higher viscosities obtained above 35% chlorine contents.The present paper represents a portion Of a comparative investigation on the preparation and study of the physical and (1) Hartman, A n indirect method of analysis for liquid mixtures of three components is described. It is applicable to ternary systems having a miscibility gap. The method requires determination of two saturation points on a solubility iso- IQUID-liquid and vapor-liquid equilibria in ternary systems

Mutual Solubility in the Ternary System n-Propyl Alcohol-Water-Hexamethyldisiloxane.

“…The research of Grubb, Chittum, and Hunt (7), Hunt (2), Hunt and Boncyk (3), Hunt and Larsen (4), Johnson and Krumboltz (5), Linhard (6), Linhard and Stephan (7), Patscheke (7? ), Patscheke and Tanne (9), Plank and Hunt (70), and Ritchey and Hunt (77) indicates that Reactions 1 and 2 may be carried out in liquid ammonia at temperatures ranging from -33°to 50°C.…”

Indirect Analysis of a Homogeneous Ternary Mixture

“…From the above, we conclude that the determination of a calibration curve practically implies the knowledge of the solubility curve. However, this knowledge is enough to determine , the composition of a saturated homogeneous ternary mixture (SHTM). To do this, it is enough to prepare a second SHTM starting from the SHTM that must be analyzed.…”

“…Many years ago Smith elaborated a method to evaluate the compositions of the two SHTMs. He considered that all the compositions corresponding to the solubility curve satisfy an equation of the type In eq , α and K are constants, w 1 and w 3 being the mass fractions of the two immiscible liquids and w 2 the mass fraction of the amphiphilic liquid.…”