Fluorinated nitrile (C 4 F 7 N) gas mixture has been introduced as the most promising candidate to replace sulfur hexafluoride using in gas-insulated equipment. In this study, the authors explored the influence of oxygen on the dielectric and decomposition properties of C 4 F 7 N-CO 2-O 2 gas mixture. The authors found that the dielectric strength of the C 4 F 7 N-CO 2-O 2 gas mixture with 2, 4, 6, 8 and 10% O 2 was increased by 4.85%, 6.49%, 7.70%, 3.21% and 2.74% compared with C 4 F 7 N-CO 2. The addition of 2-6% O 2 to the C 4 F 7 N-CO 2 gas mixture could effectively reduce the content of most of the decomposition byproducts such as CF 4 , CO, C 2 F 6 , C 3 F 6 , C 3 F 8 , CF 3 CN, C 2 F 5 CN, (CN) 2. While high content of oxygen (>6%) results in higher decomposition of C 4 F 7 N, which has a negative effect on the stability of C 4 F 7 N gas mixture. Generally, it is recommended to add 2-6% O 2 in the C 4 F 7 N-CO 2 gas mixture to improve its insulation properties as well as inhibit the decomposition of C 4 F 7 N in the discharge for medium-voltage engineering application.