Analysis of the electron-paramagnetic-resonance lineshape of Tb4+ in polycrystalline TbO2

Azzoni, C. B.; Nero, G. L. Del; Lanzi, G.; Cola, Mario Di

doi:10.1007/bf02755252

Cited by 3 publications

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“…There are rather few EPR studies so far. In addition to those already mentioned, EPR of Tb 4+ in cubic Th02 [3,4] Reprint requests to Prof. W. Müller-Warmuth. and Ce02 [5,6] was reported and furthermore in CaF2 [7,8], More recent work deals with BaTb03 [9,10], SrTbOa [9], and SrMgF4 [11],…”

Section: Introductionmentioning

confidence: 92%

EPR Studies of Tb⁴⁺ in Single Crystals of Zircon and Scheelite Structure Silicates and Germanates

Hansen

Mosel

Müller‐Warmuth

et al. 1996

Zeitschrift Für Naturforschung A

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In memoriam Professor Gerhard LehmannElectron paramagnetic resonance spectra of tetravalent terbium ions have been observed in host crystals of ZrSi0 4 , HfSi0 4 , ThSi0 4 , ThGe0 4 (zircon structure) and ZrGe0 4 , HfGe0 4 (scheelite structure) at X band and Q band and various temperatures. The spin Hamiltonian parameters have been determined from the rotational diagrams; the zero field splittings turned out to be extremely large, so that complex spectra far from the strong magnetic field limit had to be analyzed. In all the compounds Tb 4+ substitutes for the tetragonal metal lattice sites. The incorporation of terbium, the origin of the large second-order parameters and comparisons with the spectra of trivalent gadolinium in similar systems are discussed.

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Section: Introductionmentioning

confidence: 92%

EPR Studies of Tb⁴⁺ in Single Crystals of Zircon and Scheelite Structure Silicates and Germanates

Hansen

Mosel

Müller‐Warmuth

et al. 1996

Zeitschrift Für Naturforschung A

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Recent Advances in the Chemistry of the Less-Common Oxidation States of the Lanthanide Elements

Johnson

1977

Advances in Inorganic Chemistry and Radiochemistry

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Chapter 27 The binary rare earth oxides

Eyring

1979

Handbook on the Physics and Chemistry of Rare Earths

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Analysis of the electron-paramagnetic-resonance lineshape of Tb4+ in polycrystalline TbO2

Cited by 3 publications

References 1 publication

EPR Studies of Tb⁴⁺ in Single Crystals of Zircon and Scheelite Structure Silicates and Germanates

EPR Studies of Tb⁴⁺ in Single Crystals of Zircon and Scheelite Structure Silicates and Germanates

Recent Advances in the Chemistry of the Less-Common Oxidation States of the Lanthanide Elements

Chapter 27 The binary rare earth oxides

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Analysis of the electron-paramagnetic-resonance lineshape of Tb4+ in polycrystalline TbO2

Cited by 3 publications

References 1 publication

EPR Studies of Tb 4+ in Single Crystals of Zircon and Scheelite Structure Silicates and Germanates

EPR Studies of Tb 4+ in Single Crystals of Zircon and Scheelite Structure Silicates and Germanates

Recent Advances in the Chemistry of the Less-Common Oxidation States of the Lanthanide Elements

Chapter 27 The binary rare earth oxides

Contact Info

Product

Resources

About

EPR Studies of Tb⁴⁺ in Single Crystals of Zircon and Scheelite Structure Silicates and Germanates

EPR Studies of Tb⁴⁺ in Single Crystals of Zircon and Scheelite Structure Silicates and Germanates