1989
DOI: 10.1063/1.100914
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Analysis of the H2 vibrational distribution in a hydrogen discharge

Abstract: The H2(v″) vibrational distribution observed in a medium-density hydrogen discharge is analyzed in terms of standard collisional processes. All processes in the model are specified independently of adjustable parameters. The calculated distribution is found to be a sensitive function of the wall relaxation process. The warm-gas-temperature discharge analyzed here leads to a substantially more rapid H2(v″) wall relaxation than is inferred from cold-gas systems.

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Cited by 62 publications
(49 citation statements)
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“…The wall quenching coefficient c q is the probability that represents the de-excitations in collisions of the vibrational excited molecules or the excited atoms with the wall. c q of H 2 , c q; H 2 , is varied with v, and the relevant data from Hiskes and Karo, 62 and Taccogna et al 63 were used in the model. The excited atoms undergoing collisions with the wall were assumed to be de-excited to the ground states, so that c q; H ¼ 1.…”
Section: Surface Reaction Of the Neutral Speciesmentioning
confidence: 99%
“…The wall quenching coefficient c q is the probability that represents the de-excitations in collisions of the vibrational excited molecules or the excited atoms with the wall. c q of H 2 , c q; H 2 , is varied with v, and the relevant data from Hiskes and Karo, 62 and Taccogna et al 63 were used in the model. The excited atoms undergoing collisions with the wall were assumed to be de-excited to the ground states, so that c q; H ¼ 1.…”
Section: Surface Reaction Of the Neutral Speciesmentioning
confidence: 99%
“…This distribution can be easily inverted, i.e. the energy of the reflected particle can be calculated according to [18] and [19]) During the simulation the motion of all particle is fully resolved. The size of the spatial cell is smaller that Debye length.…”
Section: Wallmentioning
confidence: 99%
“…͑5͒ The average number of wall collisions by a test molecule is used to estimate the wall deexcitation of the vibrational level (vЉ). 12 The wall deexcited molecules are then redistributed among lower vibrational states according to weight factors w i (0Ͻw i Ͻ1; ⌺w i ϭ1). w i varies exponentially with vЉ.…”
Section: A Neutral Transport Codementioning
confidence: 99%