The use of spectroscopic ellipsometry for the accurate determination of the optical properties of liquid and solid metals is discussed and illustrated with previously published data for Li and Na. New data on liquid Sn and Hg from 0.6 to 3.7 eV are presented. Liquid Sn is Drudelike. The optical properties of Kg deviate from the Drude expressions, but simultaneous measurements of reflectance and ellipsonietric parameters yield consistent results with no evidence for vectorial surface effects.