“…Several studies have reported the ability of near infrared (NIR) spectroscopy which works in the spectral range 13000–4000 cm −1 , to predict, with the help of multivariate calibration methods, the presence of different bioactive compounds in tea such as catechins, caffeine, free amino acids and theaflavins [ 10 , 11 , 12 , 13 , 14 , 15 ]; this technique has been also used to discriminate different tea varieties, also in relation with the geographical origins, and to identify tea grades and tea processing degree [ 10 , 16 , 17 , 18 ]. Conversely, to the best of our knowledge, only a few studies can be found in the literature regarding the use of FTIR spectroscopy in the MIR region (spectral range 4000–400 cm −1 ) to investigate tea leaves and tea brews and to highlight differences due to processing, cultivation site and extraction methods [ 4 , 16 , 18 , 19 , 20 , 21 , 22 ]. One advantage of FT-MIR spectroscopy is its ability to provide with one single acquisition the real chemical fingerprint of the analysed material, since it is very sensitive to the chemical composition of the sample as it contains the fundamental vibrations of almost all the functional groups [ 23 ].…”