The nonleptonic weak decays of charmed mesons into a scalar meson and a pseudoscalar meson are studied. The scalar mesons under consideration are σ [or f 0 (600)], κ, f 0 (980), a 0 (980) and K * 0 (1430). A consistent picture provided by the data suggests that the light scalars below or near 1 GeV form an SU(3) flavor nonet and are predominately the q 2q2 states, while the scalar mesons above 1 GeV can be described as a qq nonet. Hence, we designate q 2q2 to σ, κ, a 0 (980), f 0 (980) and qq to K * 0 . Sizable weak annihilation contributions induced from final-state interactions are essential for understanding the data. Except for the Cabibbo doubly suppressed channel D + → f 0 K + , the data of D → σπ, f 0 π, f 0 K, K * 0 π can be accommodated in the generalized factorization approach. However, the predicted rates for D → a 0 π, a 0 K are too small by one to two orders of magnitude when compared with the preliminary measurements. Whether or not one can differentiate between the two-quark and four-quark pictures for the f 0 (980) produced in the hadronic charm decays depends on the isoscalar f 0 −σ mixing angle in the qq model.