Analysis of Voltile Organic Sulfur Compounds by Gas Partition Chromatography

Gas–Liquid Chromatography of Heterocyclic Compounds

“…the order of their boiling points, i.e., the elution order of the components studied was determined by volatility and dispersion interactions. 75 The differences in relative retention volumes for benzene and thiophene sharply increase in the order hexatriacontane 76 < dioctyl phthalate 77 < tricresylphosphate 78 < benzyldiphenyl 76 < Tween 80 77 < Reoplex 400. 78 These differences are best explained by a dipole-dipole type of interaction (μ of thiophene is 0.54 D, that of benzene, 0).…”

“…Later on Ryce and Bryce used tricresyl phosphate on Celite 545 as the stationary phase for separating mercaptans, sulfides, disulfides, and thiophane. 75 This phase easily separated sulfur compounds from light hydrocarbons and lower alcohols and benzene from thiophene at 77°C. Another polar phase, β,β'-iminodipropionitrile, was used by Karchmer to separate sulfur compounds (28.6% of ß,/^-iminodipropionitrile was used on a Celite 545 support).…”

Studies on the Cheese Flavors

“…For this reason many techniques for the analysis of microquantities of VSC have been developed (4,13,14).…”

Odors Generated During Thioglycolate Waving of Hair

“…It can be seen that the method of analysis which was selected yields the sum of the two odoriferous components expressed in terms of the equivalents of silver which is consumed due to the formation of insoluble silver sulfide or silver methyl mercaptide. FIGURE 4 shows that the odorous gases, after a brief induction period, begin to develop at a steady rate. This steady-state period continues for several hours, although only the initial 90 minutes is shown.…”