Analysis on Cellulose Crystalline and FTIR Spectra of &lt;i&gt;Artocarpus heterophyllus&lt;/i&gt; Lam Wood and Its Main Chemical Compositions

Chen, Cong Jin; Luo, Jian; Huang, Xiu Ping; Zhao, Shu Kai

doi:10.4028/www.scientific.net/amr.236-238.369

Cited by 3 publications

(1 citation statement)

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“…The crystallinity index values of cellulose in L-wood, M-wood and H-wood are 0.97, 0.98 and 1.09, respectively, which are calculated based on Nelson and O’connor method according to the Fourier transforms infrared (FTIR) spectra (Fig. 1b ) 31 . The morphology and microstructure of wood precursors were investigated with SEM and HRTEM.…”

Section: Resultsmentioning

confidence: 99%

Revealing the closed pore formation of waste wood-derived hard carbon for advanced sodium-ion battery

Tang,

Zhang,

Wang

et al. 2023

Nat Commun

189

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Although the closed pore structure plays a key role in contributing low-voltage plateau capacity of hard carbon anode for sodium-ion batteries, the formation mechanism of closed pores is still under debate. Here, we employ waste wood-derived hard carbon as a template to systematically establish the formation mechanisms of closed pores and their effect on sodium storage performance. We find that the high crystallinity cellulose in nature wood decomposes to long-range carbon layers as the wall of closed pore, and the amorphous component can hinder the graphitization of carbon layer and induce the crispation of long-range carbon layers. The optimized sample demonstrates a high reversible capacity of 430 mAh g−1 at 20 mA g−1 (plateau capacity of 293 mAh g−1 for the second cycle), as well as good rate and stable cycling performances (85.4% after 400 cycles at 500 mA g−1). Deep insights into the closed pore formation will greatly forward the rational design of hard carbon anode with high capacity.

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Section: Resultsmentioning

confidence: 99%