Analytic equation of state and thermodynamic properties for He–H2 fluid mixtures over a wide range of pressures and temperatures

Time-resolved spectral radiation histories of the gaseous H(2) + He mixtures under shock loadings were measured by using a six-wavelength channel pyrometer. The initial gaseous mixtures had a mole component of H(2):He = 1:1.21, which were shocked from room temperature and initial pressure of 20 MPa to a pressure range of 1-30 GPa and temperature range of 3000-7000 K by means of a two-stage light-gas gun. Multishock reverberations between the base-plate and sapphire window can be observed up to the fifth-shock compressions. The experimental data are in good agreement with self-consistent fluid variational theory calculations in which the dissociation process of hydrogen molecules and various interactions among atomic and molecular species are taken into account.

show abstract

The equation of state of H2+He fluid mixture in the region of partial dissociation

Gu¹,

Zheng²,

Chen³

et al. 2010

Acta Phys. Sin.

View full text Add to dashboard Cite

The H2+He fluid mixture will be dissociated into a three-component mixture composed of H2 molecules, H and He atoms at high temperatures and high pressures. The dissociation energy of H2 molecule will be lowered due to the interactions between all these particles. In this paper, the self-consistent fluid variational theory is used to calculate the equation of state of H2+He fluid mixture in the region of partial dissociation, in which the various interactions between particles and the correlation contributions to the dissociation energy caused by both the temperature and pressure effects are taken into account. The dissociation degree and thermodynamic parameters are obtained from nonideal dissociation equilibrium, which is determined self-consistently by the free energy function. Comparison was made with the available shock-wave experiments, other theoretical calculations and Monte Carlo simulations.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Analytic equation of state and thermodynamic properties for He–H2 fluid mixtures over a wide range of pressures and temperatures

Cited by 3 publications

References 22 publications

Theoretical and analytical Radial Distribution Function for non-polar mixtures

Theoretical and analytical Radial Distribution Function for non-polar mixtures

Multishock comparison of dense gaseous H2+He mixtures up to 30 GPa

The equation of state of H2+He fluid mixture in the region of partial dissociation

Contact Info

Product

Resources

About