This analytical note shall provide a contribution to the understanding of general principles in the Mechanics of (symmetric circular) masonry arches. Within a mainstream of previous research work by the authors (and competent framing in the dedicated literature), devoted to investigate the classical structural optimization problem leading to the least-thickness condition under self-weight (“Couplet-Heyman problem”), and the relevant characteristics of the purely rotational five-hinge collapse mode, new and complementary information is here analytically derived. Peculiar extremal conditions are explicitly inspected, as those leading to the maximum intrinsic non-dimensional horizontal thrust and to the foremost wide angular inner-hinge position from the crown, both occurring for specific instances of over-complete (horseshoe) arches. The whole is obtained, and confronted, for three typical solution cases, i.e., Heyman, “CCR” and Milankovitch instances, all together, by full closed-form explicit representations, and elucidated by relevant illustrations.