Analytical application of poly[dibenzo-18-crown-6] for column chromatographic separation of Nd(III) from Ce(III), U(VI) and other elements

Abstract

This research is dedicated to the study of analytical application of poly[dibenzo-18-crown-6] for separation of Nd(III) from possible lanthanides, actinides and other metal ions. A simple and efficient column chromatographic method has been developed using poly [dibenzo-18-crown-6] as stationary phase and hippuric acid as a counter ion. The capacity of crown polymer for Nd(III) was found to be 0.55 ± 0.01 mmol/g. Nd(III) was quantitatively separated from Ce(III), U(VI) and other elements in binary as well as multicomponent mixtures. Separation yields were good and reproducible (±2 %). This method has important application for separation of Nd(III) from Ce(III) rapidly and selectively.