This paper discusses experimental and simulated data regarding the thermal bridging effect in a reinforced concrete corner pillar, which belongs to a building dating back to the 1980s and located in Southern Italy. The thermal field determined by the concrete pillar corner has been evaluated, introducing an experimental procedure based on both direct measurements and indirect observations of the inner superficial temperature by means of thermal imaging techniques and surface temperature probes. Moreover, indoor and outdoor air temperature and relative humidity were measured to provide suitable boundary conditions in the numerical simulations, performed with a commercial software tool widely used in Italy based on 2D finite element techniques. The experimental measurements show that, at more than 50 cm from the corner, the surface temperatures become almost constant, meaning that the thermal bridging effect becomes less evident. However, the surface temperature in the corner is around 1.5 °C lower than in the undisturbed flanking walls. In terms of local heat flux, the discrepancy between simulations and measurements is below 3%. Finally, this paper verifies the effectiveness of External Thermal Insulation Composite System (ETICS) renovation in reducing the thermal bridging effect of the corner pillar. The results also include the calculation of the linear thermal transmittance with a series of relations available in well-known atlases for thermal bridges and show that these relations are more reliable in the case of uninsulated pillar than for the insulated one.