Analytical methods for the monitoring of post-combustion CO2 capture process using amine solvents: A review

Cuccia, Lorena; Dugay, J.; Bontemps, Domitille; Louis-Louisy, Myriam; Vial, Jérôme

doi:10.1016/j.ijggc.2018.03.014

Cited by 29 publications

(10 citation statements)

References 88 publications

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“…27 The reported value for MEA is 5 MJ/kg CO2 , while MDEA presents values of 2.8 MJ/kg CO2 with stripper temperatures between 100 and 120°C. 28 A similar behaviour presents the CO 2 loading capacity with values close to 0.6 mol CO2 /mol amine for amine primaries 29 and 0.7 mol CO2 /mol amine for tertiary amines. 30 Despite this, primary and secondary amines are mainly used because carbamate formation exceeds those of bicarbonate.…”

Section: Model Development Of the Amine-scrubbing And Co 2 Compressio...mentioning

confidence: 52%

Energy and economic analysis feasibility of CO₂capture on a natural gas internal combustion engine

García‐Mariaca

Llera‐Sastresa

2022

Greenhouse Gases

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CO2 capture by amine scrubbing is a widely developed technology in its most advanced stage of evolution. However, it has never been used to capture CO2 from mobile sources. The present study performs a thermo-economic analysis of an amine scrubbing CO2 capture storage (CCS) system, which takes for the amine regeneration process the waste heat from the exhaust gases of a turbocharged natural gas internal combustion engine (mobile source). The selected engine for the study is an M936G, widely used in freight and passenger transport. A primary and a tertiary amine were chosen for the simulations. In order to reduce volume and increase autonomy, captured CO2 is stored as a liquid; therefore, a specific installation is planned. The system is hybridised with an Organic Rankine Cycle (ORC) to reduce the energy penalty on the CCS system. Results show that a CCS system operating with Monoethanolamine (MEA) at 30 wt% achieved a maximum CO2 capture rate of 66%, with a penalty over the power engine of only 10%. On the other hand, the economic analysis showed that the CCS system with MEA and without ORC is 31.8% cheaper than a hydrogen fuel cells bus and 26% cheaper than a battery-electric bus.

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Section: Model Development Of the Amine-scrubbing And Co 2 Compressio...mentioning

confidence: 52%

Energy and economic analysis feasibility of CO₂capture on a natural gas internal combustion engine

García‐Mariaca

Llera‐Sastresa

2022

Greenhouse Gases

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“…Indirect techniques involve mass balances from the thermodynamic system from measurements of CO 2 in the gas phase and the overall CO 2 fed to the system, the difference between these amounts is equal to CO 2 in the liquid phase. Typical techniques employed for measuring CO 2 in the gas phase [1] are the following: Fourier transform infrared (FTIR) carbon dioxide sensors, gas chromatography (GC) and, protontransfer-reaction time-of-flight mass spectrometer (PTR-TOF-MS). Meanwhile, the direct techniques involve the CO 2 experimental measurement in the liquid phase, some of the analytical techniques used for this purpose are: attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy [2,3], conductivity [4,5], high-performance liquid chromatography (HPLC) [6] and titrimetric analysis [7].…”

Section: Introductionmentioning

confidence: 99%

Description of an Experimental Method to Measure the CO2 Loading in Monoethanomine Solutions using BaCO3 Titration Technique

Díaz-Herrera

Zavala‐Guzmán

Mazur-Czerwiec

2022

J. Basic Appl. Sci.

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One of the main criteria for the selection of a suitable solvent is the CO2 solubility capacity or CO2 loading. The objective of this work is to provide students and early-career scientists a detailed description of a titration-based experiment to measure the CO2 loading using simple and inexpensive volumetric and gravimetric lab apparatus. The performance of the method is corroborated by comparing the experimental uncertainty obtained during the determination of the CO2 concentration in test samples (in an absorption unit at lab scale) with reference values obtained by mass balance based on a certified gas analyser. The results indicate that CO2 loading values between the experimental method and the reference range from ±3 to 13%, which is in good agreement with other similar methods.

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“…The output, which is a dilute CO 2 -containing gas, requires separation by means of a CCS process, which in general comprises an amine solvent process requiring a significant amount of energy. After purification and compression, the captured CO 2 is then stored subsurface (Cuccia et al, 2018). In addition to traditional amine-based CO 2 capture, there are numerous CO 2 capture technologies being developed in order to reduce the energy penalty accompanying the CCS process.…”

Section: Introductionmentioning

confidence: 99%

Negative CO2 Emissions for Transportation

Jaspers¹,

Kuo

Amladi

et al. 2021

Front. Energy Res.

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Negative emission technologies have recently received increasing attention due to climate change and global warming. One among them is bioenergy with carbon capture and storage (BECCS), but the capture process is very energy intensive. Here, a novel pathway is introduced, based on second-generation biofuels followed by carbon circulation in an indefinitely closed chain, effectively resulting in a sink. Instead of using an energy-intensive conventional CCS process, the application of an on-board solid oxide fuel cell (SOFC) running on biofuels in an electric vehicle (FCEV) could result in negative emissions by capturing a concentrated stream of CO2, which is readily stored in a second tank. A CO2 recovery system at the fuel station then takes the CO2 from the tank to be transported to storage locations or to be used for local applications such as CO2-based concrete curing and synthesis of e-fuels. Incorporating CO2 utilization technologies into the FCEVs-SOFC system can close the carbon loop, achieving carbon neutrality through feeding the CO2 in a reverse-logistic to a methanol plant. The methanol produced is also used in SOFCs, leading to an infinite repetition of this carbon cycle till a saturation stage is reached. It is determined this pathway will reach typical Cradle-to-Grave negative emissions of 0.515 ton CO2 per vehicle, and total negative CO2 emission of 138 Mt for all passenger cars in the EU is potentially achievable. All steps comprise known technologies with medium to high technology readiness level (TRL) levels, so principally this system can readily be applied in the mid-term.

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Analytical methods for the monitoring of post-combustion CO2 capture process using amine solvents: A review

Cited by 29 publications

References 88 publications

Energy and economic analysis feasibility of CO₂capture on a natural gas internal combustion engine

Energy and economic analysis feasibility of CO₂capture on a natural gas internal combustion engine

Description of an Experimental Method to Measure the CO2 Loading in Monoethanomine Solutions using BaCO3 Titration Technique

Negative CO2 Emissions for Transportation

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Analytical methods for the monitoring of post-combustion CO2 capture process using amine solvents: A review

Cited by 29 publications

References 88 publications

Energy and economic analysis feasibility of CO2capture on a natural gas internal combustion engine

Energy and economic analysis feasibility of CO2capture on a natural gas internal combustion engine

Description of an Experimental Method to Measure the CO2 Loading in Monoethanomine Solutions using BaCO3 Titration Technique

Negative CO2 Emissions for Transportation

Contact Info

Product

Resources

About

Energy and economic analysis feasibility of CO₂capture on a natural gas internal combustion engine

Energy and economic analysis feasibility of CO₂capture on a natural gas internal combustion engine