2022
DOI: 10.1039/d2qm00183g
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Anchoring MoS2on an ethanol-etched Prussian blue analog for enhanced electrocatalytic efficiency for the oxygen evolution reaction

Abstract: Controllable defects and interface engineering are perceived as promising routes for developing efficient noble-metal-free electrocatalysts for oxygen evolution reaction (OER), the bottleneck of overall water splitting. Herein, we prepared molybdenum...

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Cited by 15 publications
(12 citation statements)
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“… Their CV curves were obtained at different scan rates in the potential range of −0.15 to −0.05 V in the non-Faradaic interval. As shown in Figure S19, the ECSA value for PBA/UiO-66/NF is obviously larger than those for UiO-66/NF and PBA/NF, suggesting that the increased ECSA is one of the important reasons for the improved electrochemical performance because a larger ECSA result means more active sites …”
Section: Resultsmentioning
confidence: 98%
See 1 more Smart Citation
“… Their CV curves were obtained at different scan rates in the potential range of −0.15 to −0.05 V in the non-Faradaic interval. As shown in Figure S19, the ECSA value for PBA/UiO-66/NF is obviously larger than those for UiO-66/NF and PBA/NF, suggesting that the increased ECSA is one of the important reasons for the improved electrochemical performance because a larger ECSA result means more active sites …”
Section: Resultsmentioning
confidence: 98%
“…As shown in Figure S19, the ECSA value for PBA/ UiO-66/NF is obviously larger than those for UiO-66/NF and PBA/NF, suggesting that the increased ECSA is one of the important reasons for the improved electrochemical performance because a larger ECSA result means more active sites. 61 Then, the electrochemical impedance spectrum (EIS) is tested to further evaluate the catalytic activity of electrodes. EIS is considered to be a powerful parameter to evaluate the electrode kinetics during the electrocatalytic reaction.…”
Section: Electrochemical Behavior Of Pba/uio-66/nf Toward H 2 Omentioning
confidence: 99%
“…5 Nevertheless, commercial catalysts are typically made with noble metals, which are expensive and scarce for extensive applications. 6,7 Consequently, exploring more efficient, cost-effective, and abundant non-precious metal-based catalysts with superior activity and stability is necessary. [8][9][10] Various transition metal composites have been found to be promising candidates due to their low cost, abundant earth reserves and high electrocatalytic activity.…”
Section: Introductionmentioning
confidence: 99%
“…4,[16][17][18][19][20] On the other hand, most PBAs have low electrical conductivity, a short cycle life, and poor stability in alkaline and neutral solutions, preventing them from achieving the desired energy/power densities. 21,22 Mainly, the electrochemical stability deteriorates with increasing cycles due to the rapid redox reactions at the electrode-electrolyte interface. Integrating PBAs with conducting polymers has been proposed as an effective way to overcome these challenges.…”
Section: Introductionmentioning
confidence: 99%