Anderson type polyoxomolybdate as cathode material of lithium battery and its reaction mechanism

“Wiring” redox-active polyoxometalates to carbon nanotubes using a sonication-driven periodic functionalization strategy

“…The first discharge capacity of is 3014.1 mA h g À1 ; in the second cycle, the discharge capacity decreases to 1052.6 mA h g À1 . This behaviour is well known and is associated with the formation of a solid-electrolyte interface 42 (see below) Over subsequent cycles, the specific capacity stabilized at ca. 850 mA h g À1 (Table 2 and Fig.…”

“…0.7 V in the first reduction run, which indicates the formation of a solid electrolyte interphase (SEI). 42 However, this peak disappears in the subsequent cycles. The reduction signal between 0.0-0.2 V can be attributed to the Li + insertion reaction.…”

Pyrene‐Anderson‐Modified CNTs as Anode Materials for Lithium‐Ion Batteries

“…However,t he capacity then increases slightly up to the 60th cycle, which might be due to the improved distribution of the electrolyte. [12] Up to 100 cycles, the capacity remains stable and ac apacity of 665.3 mA hg À1 is achievedw ith ac apacity retention of 35.1 %.…”

“…Typically,P OMs can reversibly store multiplee lectrons and the structurali ntegrity of the cluster is maintained. [11] Recently,S onoyama et al reported an Anderson-type POM cluster Na 3 [AlMo 6 O 24 H 6 ]a sapromising cathode materialf or LIBsw ith excellent long-term performance and am ajor voltage plateaua t% 2.0 V, [12] which features six redoxc ouplesi no ne [AlMo 6 O 24 H 6 ] 3À and corresponds to the insertionof1 8Li + into the Anderson structure.…”

High Volumetric Energy Density of LiFePO4/KB Cathode Materials Based on Ketjen Black Additive

“…By contrast with samples without KB added under the same conditions, it can be speculated that it is the van der Waals forces between KB that make the primary particles of LiFePO 4 aggregate closely. As the chain‐like structures of KB aggregate and interconnect to form a 3D network structure due to van der Waals forces, the primary particles of LiFePO 4 coated by KB also aggregate together, as seen in Figure . In addition, amorphous carbon were coated on the surfaces of the primary particles after the high‐temperature carbonization of glucose, which played a synergistic role with KB in terms of electron transport, as shown in Figure .…”