Resonant energy transfer between cold Rydberg atoms was used to determine Rydberg atom energy levels, at precisions approaching those obtainable in microwave spectroscopy. Laser cooled 85 Rb atoms from a magneto-optical trap were optically excited to 32d 5/2 Rydberg states. The two-atom process 32d 5/2 + 32d 5/2 → 34p 3/2 + 30g is resonant at an electric field of approximately 0.3 V/cm. This process is driven by the electric dipole-dipole interaction, which is allowed due to the partial f character that the g state acquires in an electric field. The experimentally observed resonant field, together with the Stark map calculation is used to make a determination of the 85 Rb ng-series quantum defect: δg(n = 30) = 0.00405(6).