Anion-controlled assembly of silver-di(aminophenyl)sulfone coordination polymers: Syntheses, crystal structures, and solid state luminescence

Zhang, Qilong; Hu, Peng; Zhao, Yi; Feng, Guangwei; Zhang, Yun‐Qian; Zhu, Bin; Tao, Zhu

doi:10.1016/j.jssc.2013.11.027

Cited by 24 publications

(2 citation statements)

References 36 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…For example, 3APS (as well as dapsone) silver coordination polymers show luminescent properties, so they are of interest because of their potential applications in chemical sensors, photochemistry, and electroluminescent displays. 11 Other applications of 3APS vary from the preparation of analogues of Congo red 12 and hybrid organic−inorganic materials. 13−15 Interestingly, although the structural similarity between 3APS and dapsone could make it possible to foresee for the first compound the existence of a rich variety of solid forms (the neutral dapsone molecule has five polymorphs), only one crystal phase containing neutral 3APS molecules is known.…”

Section: ■ Introductionmentioning

confidence: 99%

“…Finally, dapsone is also an interesting molecule from a solid-state point of view since its rich solid forms variety, which comprises several anhydrates and solvates and one hydrate. , The structurally related 3,3′-diaminophenyl sulfone, C 12 H 12 N 2 O 2 S (3APS in the following, Scheme ), which differs in the relative position of the amine group on the aromatic ring, is also an interesting molecule. For example, 3APS (as well as dapsone) silver coordination polymers show luminescent properties, so they are of interest because of their potential applications in chemical sensors, photochemistry, and electroluminescent displays . Other applications of 3APS vary from the preparation of analogues of Congo red and hybrid organic–inorganic materials. − …”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Molecular-Level Investigation of Hydrate–Anhydrous Phase Transformations of the Dapsone Structurally Related Compound 3,3′-Diaminophenyl Sulfone

Paoli

Lippi

Milazzo

et al. 2022

Crystal Growth & Design

View full text Add to dashboard Cite

The solid state of a novel hydrate form of 3,3′diaminophenyl sulfone (3APS_0.5H 2 Oo) as well as its temperatureinduced phase transitions is reported. On increasing the temperature, first a partial dehydration occurs, leading to the partially hydrated 3APS_0.1H 2 Oo, which then transforms into the monoclinic anhydrous form, 3APS_Am. Finally, by recrystallization of the melt 3APS_Am, a second anhydrous orthorhombic phase is obtained (3APS_Ao). This last phase transforms in 3APS_Am at a temperature between 360 and 400 K. XRD, DSC, TGA, HSM, and in silico data have been used to better understand the dehydration mechanism. With the same aim, hydration/ dehydration tests have been carried out. Finally, the dehydration behavior of 3APS_0.5H 2 O has been discussed in comparison with that of the dapsone hydrated phase 4APS_0.33H 2 Om.

show abstract

Section: ■ Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Molecular-Level Investigation of Hydrate–Anhydrous Phase Transformations of the Dapsone Structurally Related Compound 3,3′-Diaminophenyl Sulfone

Paoli

Lippi

Milazzo

et al. 2022

Crystal Growth & Design

View full text Add to dashboard Cite

show abstract

Synthesis, Structures, and Photoluminescent Properties of Three Coordination Polymers based on an Asymmetric Semi‐rigid V‐shaped Tricarboxylate Ligand

Shi¹,

Sun²,

Zhao³

et al. 2014

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

Three coordination polymers, [Zn(HL)(phen)(H2O)]n (1), [Zn1.5(L)(4, 4′‐bpy)1.5]n·4nH2O (2), and [Zn2(HL)2(bib)2]n·2nH2O (3), were assembled from the asymmetric semi‐rigid V‐shaped tricarboxylate ligand 4‐(2‐carboxy‐phenoxy)‐isophthalic acid (H3L) with 1, 10‐phenanthroline (phen), 4, 4′‐bipyridine(4, 4′‐bpy) and 1, 4‐bis (imidazol‐1‐yl) benzene (bib) as auxiliary ligands. Complex 1 features a one‐dimensional (1D) double‐looped chain, which is further extended into a 2D supramolecular layer via two kinds of hydrogen‐bonding interactions. Complex 2 exhibits a complicated 3D framework, which can be rationalized as a (3, 4,4)‐connected trinodal net with a unique (4·8·10) (4·8·10·123) (82·122·14·16) topology. Complex 3 has a two‐dimensional (2D) (4, 4) layer formed by the {Zn2} dinuclear SUBs and the bib ligands. The structural and topological differences of the three complexes indicate that the N‐containing auxiliary ligands play important roles in the formation of the final framework structures. In addition, complexes 1–3 were characterized by elemental analysis, IR spectroscopy, and X‐ray powder diffraction. The thermal behaviors and luminescent properties of complexes 1–3 were also investigated in detail.

show abstract

Organic free decavanadate based materials: Inorganic linkers to obtain extended structures

Yerra

Das

2017

Journal of Molecular Structure

View full text Add to dashboard Cite

Anion-controlled assembly of silver-di(aminophenyl)sulfone coordination polymers: Syntheses, crystal structures, and solid state luminescence

Cited by 24 publications

References 36 publications

Molecular-Level Investigation of Hydrate–Anhydrous Phase Transformations of the Dapsone Structurally Related Compound 3,3′-Diaminophenyl Sulfone

Molecular-Level Investigation of Hydrate–Anhydrous Phase Transformations of the Dapsone Structurally Related Compound 3,3′-Diaminophenyl Sulfone

Synthesis, Structures, and Photoluminescent Properties of Three Coordination Polymers based on an Asymmetric Semi‐rigid V‐shaped Tricarboxylate Ligand

Organic free decavanadate based materials: Inorganic linkers to obtain extended structures

Contact Info

Product

Resources

About