Anion-dependence of the polymeric structures of manganese(II) complexes of N,N′-butylenebis(imidazole)

Ballester, Loreto; Baxter, Ian; Duncan, Patrick C. M.; Goodgame, D. M. L.; Grachvogel, David A.; Williams, David J.

doi:10.1016/s0277-5387(98)00157-0

Cited by 53 publications

(15 citation statements)

References 13 publications

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“…Furthermore, the adjacent 2D layers are connected via an additional pair of bbi ligands along the c axis to form the resultant 3D supramolecular architectures with the inter-layer distance of 14.0271(15) Å (Figure 4). From the topological point of view, the 3D structure of 1 can be reduced to a (4,4) 27, 28 The structures of these complexes comprise two equivalent, mutually interpenetrating three-dimensional networks, while polymer 1 forms an open, microporous structure.…”

Section: 17mentioning

confidence: 99%

Synthesis, Crystal Structure and Luminescent Property of A Novel Cd(II) Coordination Polymer with Bis-imidazole Ligand

Zhou¹

2013

Bulletin of the Korean Chemical Society

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Research related to metal-organic coordination polymers has been a subject of great interest, not only from the view of potential applications, but also because of their intriguing architectures and framework topologies.1-3 The key to the successful design of metal-organic coordination polymers is the judicious selection of organic ligand.4 Recently, polydentate aromatic nitrogen heterocyclic ligands with fivemembered rings have been well-studied in the construction of supramolecular structure for their N-coordinated sites apt to coordinating to transition metals. Similar to six-membered N-heterocyclic ligands, the azole-based five-membered N-heterocyclic ligands, such as imidazoles, triazoles and tetrazoles have been extensively employed in the construction of various coordination polymers with diverse topologies and interesting properties.5-15 The bis(azole) ligands in which N-donor azole rings (imidazole, triazole, or tetrazole) are separated by alkyl, (CH 2 ) n , spacers are good choices for flexible bridging ligands. The conformational flexibility of the spacers makes the ligands adaptable to various coordination networks with one-, two-, and three dimensional structures. There are an increasing number of recently characterized, interesting frameworks incorporating flexible bridging ligands and metal ions have been reported. 16,17

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Section: 17mentioning

confidence: 99%

Synthesis, Crystal Structure and Luminescent Property of A Novel Cd(II) Coordination Polymer with Bis-imidazole Ligand

Zhou¹

2013

Bulletin of the Korean Chemical Society

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“…The flexible bis(imidazole) ligands 1,4-bis(imidazol-1-ylmethyl)benzene, [8][9][10][11] 1,2-bis(imidazol-1-yl)ethane [12][13][14] and 1,4-bis(imidazol-1-yl)butane [15][16][17][18][19] have been employed to obtain novel topologies. Carlucci and coworkers reported that the reaction of 1,4-bis(imidazol-1-ylmethyl)benzene with CoSO 4 forms an open-channel entangled architecture with nanoporous behavior.…”

Section: Introductionmentioning

confidence: 99%

Syntheses, Structures and Properties of Four Manganese Coordination Polymers Derived from 4‐Amino‐3,5‐bis(imidazol‐1‐ylmethyl)‐1,2,4‐triazole

Feng

Yuan

et al. 2011

Chin. J. Chem.

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“…In addition to the above mentioned fields, Im derivatives can also be used as building block in preparing ionic liquid [7], this kind of ionic liquid can act as carbene precursor [8]. Im derivatives can also be used in building coordination polymeric frameworks, significant progress has been achieved by us [9][10][11] and others [12][13][14][15][16] in this area.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Structural Characterization of Hydrazine Bridged Imidazole and its Fumarate Salt

Jin

Wang

2011

J Chem Crystallogr

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Hydrazine bridged imidazole (1) and its fumarate salt (2) have been synthesized and structurally characterized. Hydrazine bridged imidazole (1) crystallizes in the monoclinic, space group P2(1)/n, with a = 12.809(7) Å , b = 5.102(3) Å , c = 14.401(8) Å , b = 96.859(10)°, V = 934.3(9) Å 3 , Z = 2. In 1, the two imidazolyl rings are located anti-parallely above and below the benzene planes, respectively. This arrangement leads the imidazolyl rings to be in the trans conformation. In addition at each C=N bond, the larger groups linked to C and N atoms are located in the same side of the double bond, thus in the solid state the conformation of the bis-imidazole (1) is E, E. Compound 2 crystallizes in the monoclinic, space group P2(1)/n, with a = 14.272(6) Å , b = 4.815(2) Å , c = 17.816(7) Å , b = 92.329(8)°, V = 1223.4(9) Å 3 , Z = 2. For compound 2, one dimensional chain structure is formed through hydrogen bonds of N-H ? ÁÁÁO -. The chains extend in two crossed directions. These adjacent 1D parallel chains form 2D network structure under the interchain CH 2 -p associations. There also exist interchain CH 2 ÁÁÁO interactions between crossed chains. Under these weak interactions, 2 displays 3D network structure.

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Anion-dependence of the polymeric structures of manganese(II) complexes of N,N′-butylenebis(imidazole)

Cited by 53 publications

References 13 publications

Synthesis, Crystal Structure and Luminescent Property of A Novel Cd(II) Coordination Polymer with Bis-imidazole Ligand

Synthesis, Crystal Structure and Luminescent Property of A Novel Cd(II) Coordination Polymer with Bis-imidazole Ligand

Syntheses, Structures and Properties of Four Manganese Coordination Polymers Derived from 4‐Amino‐3,5‐bis(imidazol‐1‐ylmethyl)‐1,2,4‐triazole

Synthesis and Structural Characterization of Hydrazine Bridged Imidazole and its Fumarate Salt

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