Anionic phosph(in)ito (“phosphoryl”) ligands: Non-classical “actor” phosphane-type ligands in coordination chemistry

Secondary Phosphine Oxides: Bifunctional Ligands in Catalysis

“…[9] The coordination chemistry of SPOs was developed as off the 1970s and has been reviewed a number of times. [5,10] Coordination chemistry and catalysis of Fe, Ru, Os (group 8) metals has been reviewed more recently. [11] Several reviews on catalysis have appeared [12,13,14,15] and also with focus on enantioselective catalysis.…”

Coordination chemistry and catalysis with secondary phosphine oxides

“…This topic has been previously reviewed but it was either some time ago by Ackermann 7,8 or in a partial way by other authors. 6,[9][10][11][12][13] In the present review, the aim is to give an overview of the coordination behaviour of SPOs with transition metals from group 8 onwards which are those that have found more application in catalysis, discussed in the last part. Although the review is not comprehensive, we have attempted to cover the most relevant results in synthesis, coordination chemistry and catalysis with SPOs.…”

Stereospecific Protodeauration/Transmetalation Generating Configurationally Stable P‐Metalated Nucleoside Derivatives

“…[8,9] A subtle balance of electronic and steric factors controls the direction of transmetalation, and the reverse reaction has been observed [10] with boron [11,12] and transition metals including Pd, [13] Cu, [14,15] Rh, [16] Sn, [17] and Zr. [19] Even simple classification of the {P(O)(OR) 2 }group as a X or L type ligand [20a] can be challenging ( Figure 1). For [M]{P(O)(OR) 2 } species, there are additional complications that must be taken into account when predicting reactivity patterns.…”