2018
DOI: 10.1103/physrevb.98.174424
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Anisotropic magnetic properties and giant rotating magnetocaloric effect in double-perovskite Tb2CoMnO6

Abstract: We investigated the anisotropy of the magnetic and magnetocaloric properties of singlecrystalline double perovskite Tb2CoMnO6, which crystallizes in a monoclinic P21/n structure. Due to dissimilar magnetic anisotropy, the ferromagnetic order of the Co 2+ and Mn 4+ moments emerges along the c-axis at TC = 100 K, and the larger Tb 3+ moments align perpendicular to the c-axis, below TTb = 15 K. The intricate temperature development of the metamagnetism along the c-axis results in a large negative change in the ma… Show more

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Cited by 62 publications
(25 citation statements)
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“…The periodicity of angular dependence of the MCE was found in [38,39]. Giant anisotropy of magnetocaloric effect in TbMnO 3 single crystals between different axes was found [40]. These findings relate to the first order transitions near the Curie point.…”
Section: E Anisotropy Of the H-t Phase Diagrammentioning
confidence: 63%
See 1 more Smart Citation
“…The periodicity of angular dependence of the MCE was found in [38,39]. Giant anisotropy of magnetocaloric effect in TbMnO 3 single crystals between different axes was found [40]. These findings relate to the first order transitions near the Curie point.…”
Section: E Anisotropy Of the H-t Phase Diagrammentioning
confidence: 63%
“…Anisotropy of the MCE was early observed in many alloys [35][36][37][38][39][40]. It has been reported [35], that −ΔS M changes under rotating the sample in the applied magnetic field.…”
Section: E Anisotropy Of the H-t Phase Diagrammentioning
confidence: 97%
“…We have synthesized rod-like single crystals of ECMO utilizing the conventional flux method with Bi 2 O 3 flux in air 9 , 10 , 21 . The crystallographic structure of the EFO crystals was confirmed using an X-ray diffractometer (D/Max 2500, Rigaku Corp.).…”
Section: Methodsmentioning
confidence: 99%
“…Furthermore, the additional small portion of multiferroic phase which may result from the ↑↑↓↓ spin order was observed simultaneously with the ferrimagnetic phase 22 . In Gd 2 CoMnO 6 and Tb 2 CoMnO 6 , the orders of large rare-earth magnetic moments of Gd 3+ and Tb 3+ at T Gd = 21 K and T Tb = 15 K, respectively, reveal the giant anisotropic magnetocaloric effects 9 , 10 , 32 . It is evident from the previous investigations that a detailed understanding of distinct magnetic phases and interactions is essential for examining functional properties in double perovskites.…”
Section: Introductionmentioning
confidence: 99%
“…The super exchanges interactions between Co 2+ and Mn 4 + give rise to fer-romagnetic ordering in most of these materials. [14] The magnates double peroskites with heavier rare earth elements shows remarkable properties like magnetization reversal and inverse exchange based in Er 2 CoMnO 6 , [15] anisotropy magnetic properties and giant magnatocaloric effect in Tb 2 CoMnO 6 , [16] negative magnatocapaictance Yb 2 CoMnO 6 have also been observed. However Ho 2 CoMnO 6 is less studied.…”
Section: Introductionmentioning
confidence: 99%