Abstract:In this paper, we investigate the half-metallicity of Heusler alloys Keyword: half-metallicity; Heusler alloys; anisotropy magnetoresistance
1.IntroductionHalf-metallic ferromagnets were discovered by theory with the prediction of 100% spin polarization [1,2], in which the majority-spin electrons are metallic, whereas the minority-spin electrons are semiconducting. Since the first prediction of half-metallic ferromagnet in Heusler compounds in 1983 by de. Groot [3], several Heusler series that possess half-metallic properties have been experimentally realized [4][5][6]. Full-Heusler compounds are usually presented as general formula X 2 YZ, where X and Y are transition elements, Z represents main group element. The cubic unit cell consists of four interpenetrating face-centered-cubic (fcc) sublattices, two of which are occupied by identical X atoms and the other two by Y and Z atoms, respectively [7]. Because of high Curie temperature, Co-based Heusler compounds are considered as the most promising candidates for half-metallic ferromagnets working at room temperature [8,9]. However, Co-based Heusler compounds have a serious inadequacy that a high L2 1 degree of order is necessary to present a high spin polarization. For example, the recent experiments found that, in sputtered Co 2 MnSi Heusler films, a few degree of atomic disorder between Co and Mn will cause a largely reducing of the spin polarization [10]. On the other hand, the thermal excitation and spin-flip scattering can also destroy the half-metallitity in Co-based Heusler alloys. To avoid thermal excitation and spin-flip scattering of electrons to the conduction sub-band, Benjamin Bakle et al. [12] found that Fe-based Heusler alloys Fe 2 CoSi and Fe 2 CrSi are two typical half-metallic ferromagnets. They also pointed out that the half-metallitity of these Fe-based Heusler alloys is insensitive to atomic disorder. However, the Fermi level of Fe 2 CoSi and Fe 2 CrSi locate at the edge of valance and conductance bands, respectively. In this paper, using the first principles calculations, we investigate the band structures of a series Fe 2 Co 1-x Cr x Si Heusler compounds, to find the most stable half-metallic ferromagnets. The in-plane anisotropic magnetoresitance (AMR) experiments were further performed to verify the half-metallicity in this series.
ExperimentalFe 2 Co 1-x Cr x Si (x=0.0, 0.25, 0.5, 0.75, 1) ingots were prepared by arc-melting under an Ar atmosphere. Melting was repeated several times to obtain chemically homogenous ingots. Because the flaked sample for the measurements of AMR cannot be obtained by arc-melting, the melt-spinning method was utilized to make small metal sheets from the obtained ingots. The thickness of the ribbon samples used in this work is roughly around 46 μm. Structural examination was measured by x-ray diffraction (XRD) with Cu-Ka radiation. The AMR effect in all samples was measured by the standard four-terminal method in Physical Property Measurement System (PPMS). A superconducting quantum interference dev...