Achromatic quarter waveplates (A-QWPs), traditionally
constructed
from multiple birefringent crystals, can modulate light polarization
and retardation across a broad range of wavelengths. This mechanism
is inherently related to phase retardation controlled by the fast
and slow axis of stacked multi-birefringent crystals. However, the
conventional design of A-QWPs requires the incorporation of multiple
birefringent crystals, which complicates the manufacturing process
and raises costs. Here, we report the discovery of a broadband (540–1060
nm) A-QWP based on a two-dimensional (2D) layered hybrid copper halide
(HCH) perovskite single crystal. The 2D copper chloride (CuCl6) layers of the HCH crystal undergo Jahn–Teller distortion
and subsequently trigger the in-plane optical birefringence. Its broad
range of the wavelength response as an A-QWP is a consequence of the
out-of-plane mosaicity formed among the stacked inorganic layers during
the single-crystal self-assembly process in the solution phase. Given
the versatility of 2D hybridhalide perovskites, the 2D HCH crystal
offers a promising approach for designing cost-effective A-QWPs and
the ability to integrate other optical devices.