2016
DOI: 10.1007/s10593-016-1928-1
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Anisyl-, aminophenyl-, and naphthylmethylsilatranes revisited

Abstract: International audienceThree Si-substituted silatranes were synthesized in order to rectify their structure with particular attention to the length of the N-Si intramolecular dative bond. DFT calculations of potential energy profile as a function of the N-Si distance and the structure of HOMO were considered. The latter was found to vary its localization depending on the electron-donating properties of the substituent and the N-Si distance

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Cited by 3 publications
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